SOME AIRLOCKS ARE REALLY DIFFICULT TO REMOVE !
About 6 months ago, I had installed a straight extra radiator under a window, its pipework was tee-d off another rad about two feet away, along the skirting board, as the customer did not want the floor disturbed which had a new laminate on it.. This new small radiator wouldn't heat up, the system had a newish Valliant boiler. I tried everything, from venting it to shutting off the 13 other radiators in the house, but it still wouldn't work. I had to visit the house more than once ! Ultimately, in desperation, I took the radiator off the wall (closing both its valves) to check if there was sludge inside. Then, I opened the lockshield valve slightly, when a gasp of airlocked wind came out with an almighty hiss ! Upon connecting the radiator back, it worked normally !
The point is, closing all the other radiators to direct the pump pressure to the affected radiator does not always work.
I remembered old open vent 'non-combie' systems could have the pump either on the flow pipe or on the return pipe; with the pump on the flow pipe, 'positive' pump pressure would normally remove any airlock, whilst most modern combie systems have the pump on the return pipe and the 'negative' pressure does not always help in removing every kind of airlock !