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Had a Maxi Platinum combo fitted to old plumbing 5 years ago, the system was flushed and a inhibitor was added at the time.

I now need to add another radiator so as I'm draining down what's the best inhibitor/scaler to use.

I have a water softener in the house and the boiler has a Adey magnetic filtration unit fitted (which is cleaned out annually).
 
1 bottle of x100 will be fine for 10 radiators. I presume your water softener feeds your boiler, just remember you can't fill the boiler with artificially softened water so unless you have a filling loop which bypasses the water softener, you will need to shut off your softener and open the bypass valve, run the hot tap for a couple of minutes to flush any soft water out your system, and then you can fill your heating back up.
 

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