If the PRV pipe has frozen then it will be because water has leaked through the PRV if this is still in warranty and has been serviced yearly then they may have a chance of it being covered if it is not then the manufacturer will quite probably say it is not covered and if the frozen pipe was not rectified last year I would say you have no hope. If it has been a problem from day 1 then they should have been called in from the start.
Unfortunately the pressure in a boiler is constantly rising and falling ( Not to a degree that it is causing a problem) this can cause a problem with expansion vessels especially if the vessel is undersized for the system. It is a bit like a car tyre you wouldnt take that back after 2 years of use and say it went bang as if it used constantly it will have general wear and tear.