Your problem is one of incorrect venting. It is a common problem and one which cannot be solved by using air admittance valves, in fact, these are NOT to be used with septic tanks at all. Septic tank gases include methane and this gas must be allowed to disperse into the atmosphere. If you bung up the soil vent pipe, then you stop this gas escaping and are, in effect, creating a potential BOMB underground. Soil vent pipes allow air both in, as with an AAV and OUT, which is essential for septic tanks if you want to avoid an explosion. AAV's only allow air IN!
Chemicals added to the septic tank will not help with the smell, and the stink that you are experiencing from the soil vent pipe is the smell from the drains themselves. Google 'smelly drains' for answers.