1. The figures you have quoted are flow rates, not pressures.
2. To consider a combi or unvented cylinder from a "will it work" point of you you need to have satisfactory:
2a. Static pressure. This is the pressure of the incoming cold water main with no taps running. Often most easily measured at an outside tap, a washing machine / dishwasher tap or the kitchen tap.
2b. Dynamic pressure. This is the pressure of the incoming cold water main with another mains connected tap running. Most easily measured at and outside tap with the kitchen tap running.
2c. The flow rate. Should be measured at a point on the incoming main with no restrictions such as isolation valves. stopcock must be fully open.
3. Suitable pressures and flow rates are:
3a. Combi - Static pressure 1.5 bar, dynamic pressure about 1.2 bar, flow rate 15 litres / minute.
3b. Unvented - Static pressure 2.0 bar, dynamic pressure about 1.7 bar, flow rate 20 litres / minute as a minimum.
4. Pressure can only be measured with a gauge, such as Screwfix item 82412. This is designed to attach to a 3/4" BSP outlet connector such as a washing machine / dishwasher tap or outside tap. It would nee some (cheap) fittings to attach in other ways.
5. Flow rate can be measured with a weir cup such as Screwfix 5784K, or by timing how long it takes to fill a 10 litre bucket and calculating the litres / minute flow rate from that. The weir cup is a bit expensive for one off use.
6. The points Nwalky makes are good ones, but in addition:
6a. You won't get two simultaneous showers from a combi unless it is a very powerful one and you make sure both showers are limited to a a maximum hot flow rate of around 6 or 7 litres per minute.
6b. If the boiler breaks down you will have no heating or hot water until it is fixed. With a hot water cylinder system (whether vented or unvented) you have the option of an immersion heater, so that you can at least have hot water.
6c. The unvented system is a good option, but if there is a break in the water supply, you will have neither cold not hot water. With an unvented system you could have both until the cold water storage system runs dry, albeit the cold water would need boiling before drinking.
6d. An unvented hot water cylinder must only be installed by a "G3" registered installer, and should be serviced every year.
7. My personal preference is a heat only boiler running a sealed central heating system and a vented hot water system. Electric pump to boost hot, and if necessary cold, supplies. Simple, reliable, cheap although the pump(s) if necessary can be a bit noisy.