Sorry for delayed response, I can't find my way round this site very easily! I have tested the ph of the water and it came up neutral. Also, the formation of soot left me confused - I though hydrogen burned clean? Also, I have been told that if it was hydrogen it would burn rapidly (ie pop), while this burns slowly and maintains a flame - I have even managed to video it. My thoughts were methane from some kind of biological action, but it is interesting that none of you proposed this. I see fernox have an anti bacterial cleaning solution - but are such things rare? I would have thought that the power flush that preceded the boiler being fitted would have got rid of nasties, but is is a 10mm microbore system. Still think it's hydrogen? My plumber is offering an air seperator, labour free, parts only cost. Should I accept this fix?