Now here is something that happens a whole lot. As Bernie has mentioned, you may want to establish how long it has done this. It could be they are plumbed into the water circuit, common on older systems for the bathroom, or a bypass rads (Heat Leak) Turn those 2 off and see if another 2 heat up. If they do, then small amount of let by possibble ! Or if it is an S plan (You have 2 x zone valves) the bypass may be thr problem. When engineers upgraded systems, many forgot to install a bypass, the subsequent repair engineer then fits the bypass in a poor place and you get flow where it was never wise to flow. What type of system, is it y,c, s or combi ??? That should help get closer to the cause