Hello my parents have a house with an open vented system. It has an oil boiler feeding 4 circuits of radiators and also an indirect hot water cylinder. It also has a solid fuel fireplace back boiler (with 4 pipes) to it. The fire can heat both the radiator and the hot water. The fire is never lit. The feed and expansion tank is regularly overflowing every so often, mostly when the hot water heating circuit stops (I think). The feed and expansion tank gets sporadic water fill from the vent pipe and I can also feel a small pulse, or in flow, of water from the feed and expansion tank outlet. Here is a diagram. The system has been like this for years, but only started giving this problem a few months ago. Be gentle.