Thanks for the replies.
I turned the pump around as the customer said the air in the system had been happening for 2 or 3 years and then they said they had a new pump around 3 years ago. I was thinking air was being drawn down the vent and if the pump was originally the other way around then and when it was changed it was fitted the wrong way then this seemed logical, also there was red tape on the pipe so I thought it was the flow side. When I saw the pumping over I knew something was wrong, so I did some more investigation and discovered it was the return side. When I talked again with the customer I found out he put the red tape on as there was a pipe clip there and the pipe would not stay in the clip so he put red tape on hopeing it would jam in the clip better. When I siad to him that it seemed strange that this problem had only been happening for 2 or 3 years since the changing of the pump his wife said (who was not there earlier) "no it's been happening a lot longer than that"! So it was a little being misled along with my inexperiance that caused me to turn the pump around. Anyway on the up side no air was drawn in to the system during the period the pump was on the wrong way round.
Going on to some of the recommendations. I thought of an auto air vent on the rad, however it is in the main bedroom and there is so much air being drawn in to the system it could be going off when they are in bed (being a stove it takes time to cool and stop the heating process).
With the suggestion of a manual vent, would this just move the bleeding of the system from the rad to the manual vent? There is so much air (it takes about 1 minute per day to bleed the rad) then the manual vent would need bleeding every day.
I like the idea of capping off the vent, It seems logical that although there is 2 seperate circuits there is one lot of water that mixes in the boiler. The vent is basically for the water in the boiler in case it over heats so one would be sufficient.
I am fairly certain the HWC is indirect and not primatic as there is an F&E tank, if it was primatic then there would not be an F&E tank.