The simple fact is hot air rises, the principle of a chimmney is the the hot air rises in it expel the poc. Having a rad in front of the vent can not cause any problems as the hot air will convect up the chimmney as well as round the room. Me thinks a few of us might like to reconsider our opinions here or else all our old coal fires would be sucking in cold air and not working.
I have several old chimmneys which are vented with rads in front of the vent which is only there to prevent condensation build up in the chimmney once its no longer used, and the rads help keep the moisture down and have in fact helped dry off an old chimmney breast that used to leach out the soot when it was really wet.