I think the one in question is currently switching at around 65degC.
The boiler thermostat is several years old so there is a good chance that the pump overrun set point has drifted over time and is now higher than it should be.
The result is that if the boiler thermostat is set fairly low (e.g. '2' on the '1' to '5' scale), then the water temp in the heat exchanger can remain below the pump overrun threshold. When the room stat turns off the boiler, the pump turns off at the same time (i.e. no initial pump overrun). The water temp in the heat exchanger continues to rise for a while and after a few seconds the pump switches back on. It only remains on for about 25 seconds and then is switched off by the pump overrun thermostat. When this happens there is sometimes a disturbing thump noise in the vent pipe as a pocket of water vapour is expelled up into the F&E tank.
If the boiler temperature is increased slightly (e.g. setting '3'), then the problem goes away because the water temperature in the heat exchanger is above the pump overrun threshold and so the pump remains on for longer when the room stat cuts off the boiler.
The pump overrun threshold is factory set and is not intended to be modified: The adjustment screw has thread lock to stop it moving. The problem is that the thermostat is obsolete and I cannot buy a replacement.
Using an old thermostat, I have found that a soldering iron applied to the adjustment screw softens the thread lock and allows it to turn. I think I need to remove the thermostat from the boiler, place the phial in a heated pan of water and use a thermometer to adjust the screw so that it switches at a lower temperature.
Hence my original question about the correct temperature setting for the pump overrun.
You would have thought this information would be published by Ranco but I've been unable to find any documentation online.