It might help to think of the pre (charge) pressure as a adjustable spring with a piston (the diaphragm) between it and the water end, when cold water is admitted then depending on the pre charge pressure and the cold water pressure; the piston will move towards the air end compressing this (air) spring until the pressure at both ends are the same, if the pre charge pressure and the water pressure are the same then the piston will stay up against the water end, As the water in the HWC starts expanding due to being heated, it will start entering the EV and will keep pushing back the piston until all the expanded water is contained within the EV. If you look at the first set of calcs you will see that with a pre charge pressure of 2.7 bar and a cold water (filling) pressure of 3 bar will give a final pressure after expansion of 3.79 bar, if for some reason the spring tension started decreasing (ie air leak at the schrader valve) then the final pressure will start rising, if the pre charge pressure fell to 1 bar then the final pressure would be 4.76 bar, if it fell to 0.23 bar then the final pressure would be practically 7 bar and would lift the PRV. Excessive pre charge pressure can have the same effect and that's why it is very important to check the pre pressure in the EV before fitting it despite what's written on the label and ideally it should also be checked at service time.
EV's are (or should be) pre charged with nitrogen as air (which is permeable) can leak and loose its pressure through the diaphragm.