That Megaflo is a hot water cylinder that is stainless steel unvented and therefore allows you storage of hot water, unlike a solely combi gas boiler system. It has same benefits that a combi system has (balanced high pressure to hot and cold throughout the house) but better flow rates of hot water due to heated water already in storage.
Note you need to have that unit serviced once a year by an unvented qualified plumber to keep it functioning well and for safety as well as manufacturers warranty of cylinder, often 25yrs.
That unit has an air bubble that allows expansion and this depletes which is something you can correct yourself on occasions.
To heat that cylinder from cold will usually require a couple hours on programmer to be sure to fully heat it. It is thermostatically controlled, so your gas boiler will shut off once the Megaflo reached temperature.
Your gas boiler is perhaps a sealed system boiler, same as a combi, only without the hot water and would require the system pressure (that is rads and gas boiler) to be kept in pressure - usually more than 1bar, so check boiler instructions on pressure & how to top it up at boiler