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If there was a weak point in the system at low pressure you would draw in air yes.
The expansion vessel will be positioned before the pump, with the pump pumping away. The point the vessel connects to the system is the neutral point or point of no pressure change. Between the vessel and pump will be a very short section of pipework under negative pressure, the pump will then add it's differential pressure to the discharge side, this will supply a positive pressure throughout the system back to the point of no pressure change at the vessel connection point.
The expansion vessel will be positioned before the pump, with the pump pumping away. The point the vessel connects to the system is the neutral point or point of no pressure change. Between the vessel and pump will be a very short section of pipework under negative pressure, the pump will then add it's differential pressure to the discharge side, this will supply a positive pressure throughout the system back to the point of no pressure change at the vessel connection point.