Thanks everyone.
I will try and make explaining a little simpler.
Before I fitted the new Valve head,when sliding the CH on it would not fire the boiler up so I had to slide the HW along to ignite the boiler.
Now after changing the valve head.
I slide the HW to on and it does not fire the boiler the same as it used to.I then slide the CH switch along and it fires the boiler.
This is what makes me think the problem is with the valve wiring as I have not touched the programmer,
Cheers Dal