Just had my first look at the photo of the updated pipework. I can't see anything major now wrong with the heating system pipes.
The cylinder tee in last on return, as you would expect.
(There can be some heat gravitating on a return where it keeps rising, like in the photo, if it has a path)
Only thing I can think of is there are more than one main tee off to a zone causing a loop going to the On zone.
But I need to think on it sometime I get time