Perfectly sensible idea to use an existing Feed cistern to continue to automatically top up a now sealed system with the same low pressure it always had on it.
It is often shown in MI's as an option, you will note a check valve is required on the cold feed to create the seal (as you stated you have capped the old vent pipe). It is surprising that some engineers have never seen the diagrams in the boiler instructions!!
Where is the expansion vessel located ? Its gas charge will need to be adjusted to equal the static water head above it, as 1M = 0.1bar you can work it out before you refill the system with water.
One thing to remember is that the point of connection of the vessel will now be the neutral point of the system so ideally it should be located on the suction side of the pump so that as much of the system is under positive pressure as possible.
Just for your info the 418 is a regular or heat only not a system boiler that would be a 618.