Unlikely to be an airlock as the unvented cylinder is mains supplied, so pointless.
Really we shouldn't be putting mains at kitchen sink into the hot unvented supply anyhow, because the mains at kitchen is usually direct off the main stopcock - with no pressure regulator and could be at a much higher pressure than the 3bar max for stainless steel unvented cylinders. You would be bypassing the units combination valve in effect, however momentarily and pressure would build up unless a second hot tap was left open.
This might apply also to other mixer taps in a home, as not all unvented installs use the balanced cold (3bar max) from combination valve connection to every, if any taps.
Note - Putting the mains cold into the hot side of a mixer tap can only be done in most modern mixers by removing the spout and holding your hand over the tap body, as the spout is double pipe and won't allow the hot & cold to mix, unlike the old mixers that had a single chamber spout.