Many thanks John, your help is much appreciated.At 75C/55C you are getting 29.3kw rad output or 89.2% of your 33.5kw T50 rating, if you were to run at a flow temperature of 65C then you will get a return temperature of 49.4C with 22.81kw rad output or 68.1% of your 33.5kw T50 rating, so a 24kw boiler may be ok especially as you probably won't be running two zones together for very long periods.
I’ll arrange for boiler to be replaced in the new year along with reinstating the LLH and taking advice from Timmy for addding a filter to the secondary return, a ntc sensor and setting pump speed to constant. Just need to work out how to wire it up and program the boiler