Although I have opened a potable vessel that had a burst 'balloon' membrane, I can't be sure what it was like inside. It was just mild steel though. No need of it to be stainless steel while the 'balloon' stays intact, but I think for when it bursts that vessels should be stainless steel.
Certainly a weak point with unvented units!
I know that stainless steel vessels exist, but I don't think the vessels we see are that. Colour of vessel is irrelevant, - they can be any colour, although most potable are white or blue, they can be red.
I did see a Telford Copper unvented unit with vessel built in to the top of it, which had 2 vessels fail & flood a very nice house within a few years, before I worked for the owner. I replaced it with a stainless steel unit with vessel separate. I suspect heat gets at the vessels built into the top.