You have a return temperature back to the boiler that is not a true reflection of the system temp.
Hot water flow is returning back to the boiler too early without dissipating heat which means the flow is mixing with the return and raising the temperature of the return higher than it would otherwise be.
This will always be a function of the pipework route. If the route has not been changed then a valve is causing the issue.
Buy a digital thermometer and measure the temperatures along the pipe, at valves, joints etc. Where the temp rises or drops within a few centimeters is your problem point. it only takes a very small rise in return to create this issue.
As you are using low temperature water for circulation, your problem will be unimaginable to 99% of plumbers who only know about basic combi boilers and room thermostats set at 22 degrees.
If you want a more scientific approach rather than the random guesses, have a look at heat geek's site. Go back to basics, its so refreshing
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