A
Aire
Only reason I can see is the British standard thing. If it had been tested and found the pipe fails under a secondary return system then surely they would state that.They must have a reason to say must not be used.
If you think of worst case scenario
Cylinder immersions set to 70
On 24/7 and return pump on constant
The plastic pipes goes a bit floppy and you could have a fitting blow off.
At least most CH systems are sealed so you would only get a few buckets of water.
They say their pipe will function correctly for 50 years at 90°c temperature and at 6bar so even in the most extreme cases of an unvented system breakdown, the pipe should be fine.