If you mean that the boiler ran continuously for 45.37 mins then its output was ~ 19.7kwh and if all that energy was inputted to the hot water cylinder then the cylinder volume would need to be 846 liters to only rise by 20C, not likely, if the HW cylinder is say a more realistic 250 liters then it would only take 5.81kwh or 13.5 min to rise it by 20C. still not clear as to what's going on but with these valves now closed then it may be become clearer.