The thing is it would suck air in if I flipped them round to make feed first
Really wish he would seal the bloody thing 25+ rads
View attachment 33932
Ideally, should be boiler - open vent - cold feed - pump. That's the best arrangement to vent air, which is most likely to come from the boiler, specially on initial commissioning. Also as the cold feed sets the reference pressure for the system, gives lowest risk of anywhere being below atmospheric pressure, as you obviously don't want inward air leaks.
But there shouldn't be a problem putting both on the return as your original sketch, if the height between the boiler outlet and the F/E tank is adequate. The point of minimum pressure is then boiler discharge, and = static pressure from the F/E tank minus boiler headloss, so likely to be well above atmospheric with usual boiler headloss figure. 8m seems high for the pump, but if the complete system does have this friction loss, most of that won't be across the boiler.
Your 3 pump positions diagrams would be more useful if the locations of the boiler and rads were shown. Comments shown are correct, IMO.
No.1 is poor because the minimum pressure is F/E tank static pressure minus total system loss, so if loss is 8m, could be below atmospheric.
No.2 is a non-starter as there will be over-pumping if the pump head is above the height from F/E tank TWL to the top of the vent pipe, typically 0.45m, as it almost certainly will be.
No.3 is OK, could be either of your original options, depending on whether the boiler is to the left of the open vent or between the cold feed and the pump.