It was probably never set up properly, you are possibly the first person to touch it, if the no flow pump head is less than 5M (0.5bar) then the ABV will never open, so you can adjust it around that setting (of 0.3) so that it only opens when both mot.valves shut and the pump is on overrun.
Well, back to square one so re high gas consumption as the cyl temp is being controlled and even if left enabled all day shouldn't account for that excess gas usage which was mad during the summer , see post #31, even 12kw current usage seems quite high once house up to temp?.
You said you might try running on the immersion for a day or two to rule out HW usage?.
Can you also not programme the HW cylinder to be heated for a few hours in the morning?, can't remember if you said that it has its own programmed zone.
If the ABV is passing then that will consume a fair few M3 of gas via unlagged copper pipes, the easiest way to check it is when/if the system is cold in the morning and just after the boiler fires up, keep your hand on the vertical ABC (downstream) pipe which should remain cold for a long period, if not leaking it could still possibly feel very hot due to conduction.