This needs to be done in conjunction with a FGA (flue gas analyser) and I shouldn’t tell you because randomly adjusting can through all other readings out. Ideally you want maximum combustion and CO2 with no excess air, this however is not practical in the modern world and you will always have a lower CO2 and certain amount of excess air, this is down to the fact increasing CO2 also increases smoke and soot emissions. Again CO2 is set depending on ambient air temperature and density. If excess air was too high it can force heat up through the flue and reduce efficiency, it can also cool the combustion process and increase CO ppm as well as extinguish flame, the data sheet suggests your efficiency and CO are good, certainly for a non condensing boiler.