JP
I would be wary of trying to fix this by making ad hoc modifications ( new bits of pipe and valves et al ) and then trying to run the system. You run the possible risk of either making the problem worse or possibly causing expensive damage to the boiler.
Isolate the heating system other than one radiator (preferably the one closest to the boiler ) and then systematically work through the boiler + single rad hydraulic system. At the same time check and test the individual controls against the logic diagram. Also fit a quality magnetic filter on the return to the boiler.
Once you are satisfied that you have a clear hydraulic path on your mini system - configure the pump to run with the boiler off and satisfy yourself you have a good clean flow path.
Thereafter and only when you have a clear hydraulic flow path, get the boiler operational at minimum rate and stable before you systematically look at the rest of the system.
At the end of the day, you have a fairly straightforward system to analyse, approach it in a logical step by step fashion - and make sure that you have not had anyone in to work in this problem who has changed the flow paths.
Always have in mind that you may have more than one problem with the system - hence the need to be systematic, patient and don’t jump to conclusions (sludge is an issue, but in my experience, a serious sludge problem = no flow, not erratic flow which are (to my mind) the symptoms you are describing ).
A suggestion - get the new iso valve by the pump removed - it is not full bore so is restricting flow - it may seem churlish, but the last thing you need at the moment is anything that disrupts or distorts the hydraulic flow
Hope this helps